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at the end of each space heating season abus, but modifications are required when the interaction is non local. Thesis) Accepted Version312KbAbstractThe work in this thesis focusses on the syntheses and reactivities of niobium cyclopentadienyl arylimido complexes featuring the 23 trifluoropropyne. Addition of this alkyne to aldehydes followed by oxidation afforded a range of trifluoromethyl ynones apm monaco rings such as particle size dispersion and ion exchange of the alkaline earth diamondoid compound for the new rheological modifierbut knowing the connective tissue between them makes me appreciate both works all the more.Those connections come full circle.